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2-Chloro-benzene-1,4-diaminium bis-(dihydrogenphosphate).

Authors :
Mrad ML
Zeller M
Rzaigui M
Ben Nasr C
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2013 Feb 01; Vol. 69 (Pt 2), pp. o159-60. Date of Electronic Publication: 2013 Jan 04.
Publication Year :
2013

Abstract

The asymmetric unit of the title salt, C(6)H(9)ClN(2) (2+)·2H(2)PO(4) (-), contains two dihydrogenphosphate anions and one 2-chloro-benzene-1,4-diaminium dication. The H(2)PO(4) (-) anions are inter-connected through strong O-H⋯O hydrogen bonds to form two-dimensional infinite layers parallel to (001). The organic entities are anchored to the inorganic layers through N-H⋯O hydrogen bonds, and through weak C-Cl⋯O halogen bonds [3.159 (2) Å, 140.48 (7)°]. No π-π stacking inter-actions between neighboring aromatic rings or C-H⋯π inter-actions towards them are observed. Minor disorder is observed for the Cl atom and one hy-droxy group [minor-component occupancy = 3.29 (9)%].

Details

Language :
English
ISSN :
1600-5368
Volume :
69
Issue :
Pt 2
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
23424449
Full Text :
https://doi.org/10.1107/S1600536812051434