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2-Chloro-benzene-1,4-diaminium bis-(dihydrogenphosphate).
- Source :
-
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2013 Feb 01; Vol. 69 (Pt 2), pp. o159-60. Date of Electronic Publication: 2013 Jan 04. - Publication Year :
- 2013
-
Abstract
- The asymmetric unit of the title salt, C(6)H(9)ClN(2) (2+)·2H(2)PO(4) (-), contains two dihydrogenphosphate anions and one 2-chloro-benzene-1,4-diaminium dication. The H(2)PO(4) (-) anions are inter-connected through strong O-H⋯O hydrogen bonds to form two-dimensional infinite layers parallel to (001). The organic entities are anchored to the inorganic layers through N-H⋯O hydrogen bonds, and through weak C-Cl⋯O halogen bonds [3.159 (2) Å, 140.48 (7)°]. No π-π stacking inter-actions between neighboring aromatic rings or C-H⋯π inter-actions towards them are observed. Minor disorder is observed for the Cl atom and one hy-droxy group [minor-component occupancy = 3.29 (9)%].
Details
- Language :
- English
- ISSN :
- 1600-5368
- Volume :
- 69
- Issue :
- Pt 2
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section E, Structure reports online
- Publication Type :
- Academic Journal
- Accession number :
- 23424449
- Full Text :
- https://doi.org/10.1107/S1600536812051434