Back to Search
Start Over
Diaqua-(5-carb-oxy-benzene-1,3-dicarboxyl-ato-κO(1))[8-ethyl-5-oxo-2-(piperazin-4-ium-1-yl)-5,8-dihydro-pyrido[2,3-d]pyrimidine-6-carboxyl-ato-κ(2)O(5),O(6)]zinc monohydrate.
- Source :
-
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2013 Feb 01; Vol. 69 (Pt 2), pp. m127. Date of Electronic Publication: 2013 Jan 31. - Publication Year :
- 2013
-
Abstract
- In the title compound, [Zn(C(14)H(17)N(5)O(3))(C(9)H(4)O(6))(H(2)O)(2)]·H(2)O, the complex mol-ecule exists in a zwitterionic form. The Zn(II) ion exhibits a distorted tetra-gonal-pyramidal geometry, being coordinated by two O atoms from the zwitterionic 8-ethyl-5-oxo-2-(piperazin-4-ium-1-yl)-5,8-dihydro-pyrido[2,3-d]pyrimidine-6-carboxyl-ate (L) ligand, one O atom from the 5-carb-oxy-benzene-1,3-dicarboxyl-ate dianion, [Hbtc](2-), and two O atoms from two aqua ligands. In the crystal, N-H⋯O and O-H⋯O hydrogen bonds link the components into a three-dimensional structure. The crystal packing exhibits π-π inter-actions between the aromatic rings, with centroid-centroid distances in the range 3.466 (3)-3.667 (3) Å.
Details
- Language :
- English
- ISSN :
- 1600-5368
- Volume :
- 69
- Issue :
- Pt 2
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section E, Structure reports online
- Publication Type :
- Academic Journal
- Accession number :
- 23424417
- Full Text :
- https://doi.org/10.1107/S1600536813002122