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An entry to functionalized 2,8-ethanonoradamantane derivatives.

Authors :
Camps P
Gómez T
Monasterolo C
Source :
The Journal of organic chemistry [J Org Chem] 2012 Dec 21; Vol. 77 (24), pp. 11270-82. Date of Electronic Publication: 2012 Dec 10.
Publication Year :
2012

Abstract

The synthesis of a functionalized derivative containing the 2,8-ethanonoradamantane carbocyclic skeleton, whose key-step consists of an intramolecular Diels-Alder reaction, is described. Chemoselective reduction of an intermediate enone required protection of the maleimide function through their Diels-Alder adducts with furan.

Details

Language :
English
ISSN :
1520-6904
Volume :
77
Issue :
24
Database :
MEDLINE
Journal :
The Journal of organic chemistry
Publication Type :
Academic Journal
Accession number :
23198707
Full Text :
https://doi.org/10.1021/jo302398c