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Tailored nanostructuring of end-group-functionalized high-density polyethylene synthesized by an efficient catalytic version of Ziegler's "Aufbaureaktion".

Authors :
Pillai SK
Kretschmer WP
Trebbin M
Förster S
Kempe R
Source :
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2012 Oct 29; Vol. 18 (44), pp. 13974-8. Date of Electronic Publication: 2012 Sep 20.
Publication Year :
2012

Abstract

Monoguanidinato titanium complexes are efficient catalysts to make OH end-group-functionalized polyethylene (PE-OH) by a catalyzed version of Ziegler's "Aufbaureaktion". This PE-OH can be structured to mesoporous polyethylene or polyethylene nanofibers/ribbons through diblock copolymer synthesis, microphase separation, and etching of the sacrificial polylactide block.<br /> (Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Details

Language :
English
ISSN :
1521-3765
Volume :
18
Issue :
44
Database :
MEDLINE
Journal :
Chemistry (Weinheim an der Bergstrasse, Germany)
Publication Type :
Academic Journal
Accession number :
22996172
Full Text :
https://doi.org/10.1002/chem.201202506