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1-[(4-Chloro-phen-yl)(phen-yl)meth-yl]piperazine-1,4-diium bis-(trichloro-acetate)-trichloro-acetic acid (1/1).

Authors :
Song Y
Chidan Kumar CS
Akkurt M
Chandraju S
Li H
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2012 Sep 01; Vol. 68 (Pt 9), pp. o2695-6. Date of Electronic Publication: 2012 Aug 11.
Publication Year :
2012

Abstract

In the title salt adduct, C(17)H(21)ClN(2) (2+)·2C(2)Cl(3)O(2) (-)·C(2)HCl(3)O(2), the Cl atom of the dication is disordered over two positions in a 0.915 (3):0.085 (3) ratio. The Cl atoms in the trichloroacetate anions and trichloroacetic acid molecule are also disordered, with refined site-occupation factors of 0.59 (3):0.41 (3), 0.503 (12):0.417 (12) and 0.653 (12):0.347 (12). The piperazine ring adopts a chair conformation, with puckering parameters Q(T) = 0.587 (3) Å, θ = 2.6 (2) and Φ 334 (6)°. In the crystal, neighbouring mol-ecules are linked by N-H⋯O, O-H⋯O, N-H⋯Cl, C-H⋯O and C-H⋯Cl hydrogen bonds, forming a three-dimensional network.

Details

Language :
English
ISSN :
1600-5368
Volume :
68
Issue :
Pt 9
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
22969587
Full Text :
https://doi.org/10.1107/S1600536812034794