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A novel mixed valent Cu(II)-Cu(I) 2D framework made of a hydrazone and μ-SCN bridged metallacyclic loops cross-linked by μ3-SCN chains.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2012 Oct 14; Vol. 41 (38), pp. 11565-8. Date of Electronic Publication: 2012 Aug 28. - Publication Year :
- 2012
-
Abstract
- A mixed valent copper complex [Cu(II)Cu(I)(L)(μ-SCN)(μ(3)-SCN)](n) (LH = N'-((pyridin-2-yl)methylene)acetohydrazide) has been synthesized and characterized. It is a unique example of a 2D mixed valent Cu(II)-Cu(I) interlinked molecular assembly with a very unusual bridging property of the hydrazone ligand. An extraordinary in situ partial Cu(II)→ Cu(I) reduction is observed in this system at room temperature.
Details
- Language :
- English
- ISSN :
- 1477-9234
- Volume :
- 41
- Issue :
- 38
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 22930162
- Full Text :
- https://doi.org/10.1039/c2dt31666h