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A canted antiferromagnetic ordered phase of cyanido-bridged Mn(III)2Re(IV) single-chain magnets.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2012 Oct 09; Vol. 48 (78), pp. 9717-9. - Publication Year :
- 2012
-
Abstract
- A new cyanido-bridged Re(IV)-Mn(III) heterometallic 1D system, [Mn(III)(5-Me-saltmen)](2)[Re(IV)Cl(4)(CN)(2)]·3CH(3)CN (1), was designed and structurally characterized. Interchain interactions stabilize a canted antiferromagnetic ordered state below 6.2 K that does not prevent slow relaxation of the magnetization reminiscent of the single-chain magnet properties of the individual chains.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 48
- Issue :
- 78
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 22914688
- Full Text :
- https://doi.org/10.1039/c2cc34066f