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Formation of Ti28 ln cages, the highest nuclearity polyoxotitanates (Ln = La, Ce).
- Source :
-
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2012 Sep 17; Vol. 18 (38), pp. 11867-70. Date of Electronic Publication: 2012 Aug 21. - Publication Year :
- 2012
-
Abstract
- The solvothermal reactions of Ti(OEt)(4) with LnCl(3) (Ln = La, Ce) produced new Ti(28) Ln cages, in which the Ln(3+) ions are coordinated within a metallocrown arrangement, which represents the highest nuclearity cages of this type (see figure).<br /> (Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1521-3765
- Volume :
- 18
- Issue :
- 38
- Database :
- MEDLINE
- Journal :
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Publication Type :
- Academic Journal
- Accession number :
- 22907895
- Full Text :
- https://doi.org/10.1002/chem.201201827