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6-Hy-droxy-7,8-dimethyl-chroman-2-one.

Authors :
Goswami SK
Hanton LR
McAdam CJ
Moratti SC
Simpson J
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2012 Aug 01; Vol. 68 (Pt 8), pp. o2332-3. Date of Electronic Publication: 2012 Jul 04.
Publication Year :
2012

Abstract

The title compound, C(11)H(12)O(3), is essentially planar, with an r.m.s. deviation of 0.179 Å from the mean plane through the 14 non-H atoms in the mol-ecule. The benzene ring and the pyranone mean plane are inclined at 13.12 (6)° to one another and the pyran-one ring adopts a flattened chair conformation. In the crystal, O-H⋯O hydrogen bonds and C-H⋯O contacts form R(1) (2)(6) rings and link mol-ecules into chains along b. Additional C-H⋯O contacts generate inversion dimers, with R(2) (2)(8) ring motifs, and form sheets parallel to (-102) which are linked by C-H⋯π interactions.

Details

Language :
English
ISSN :
1600-5368
Volume :
68
Issue :
Pt 8
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
22904804
Full Text :
https://doi.org/10.1107/S1600536812029704