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Facile formation of five-membered N-heterocyclic zirconacycloallenoids.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2012 Sep 21; Vol. 41 (35), pp. 10811-6. Date of Electronic Publication: 2012 Aug 02. - Publication Year :
- 2012
-
Abstract
- The reaction of η(2)-iminozirconocene chloride complexes with trimethylsilylethynyl lithium leads to rapid C-C coupling at room temperature to yield the corresponding five-membered aza-zirconacycloallenoids. Such compounds were also obtained by trapping of in situ generated zirconocene with alkynyl imines.
Details
- Language :
- English
- ISSN :
- 1477-9234
- Volume :
- 41
- Issue :
- 35
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 22854597
- Full Text :
- https://doi.org/10.1039/c2dt31343j