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Ir-catalyzed direct borylation at the 4-position of pyrene.

Authors :
Liu Z
Wang Y
Chen Y
Liu J
Fang Q
Kleeberg C
Marder TB
Source :
The Journal of organic chemistry [J Org Chem] 2012 Aug 17; Vol. 77 (16), pp. 7124-8. Date of Electronic Publication: 2012 Jul 31.
Publication Year :
2012

Abstract

The first direct borylation of a C-H bond at the 4-position of pyrene was achieved using [Ir(COD)Cl](2)/dtbpy as the catalyst precursor and B(2)pin(2) as the boron source. The position-related photophysical properties of pyrene derivatives are reported.

Details

Language :
English
ISSN :
1520-6904
Volume :
77
Issue :
16
Database :
MEDLINE
Journal :
The Journal of organic chemistry
Publication Type :
Academic Journal
Accession number :
22816387
Full Text :
https://doi.org/10.1021/jo301293w