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A 32 vertex polyhedron via supramolecular assembly of silanedithiolate silanolate units.

Authors :
Spirk S
Belaj F
Hurkes N
Pietschnig R
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2012 Aug 28; Vol. 48 (67), pp. 8398-400. Date of Electronic Publication: 2012 Jul 16.
Publication Year :
2012

Abstract

A high yield synthesis of the first silanedithiolate silanolate is reported which spontaneously assembles forming an inorganic rugby ball shaped 32 vertex polyhedral cluster stabilized by sterically demanding 2,6-dimesitylphenyl substituents and two LiCl units.

Details

Language :
English
ISSN :
1364-548X
Volume :
48
Issue :
67
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
22797212
Full Text :
https://doi.org/10.1039/c2cc33883a