A new hybrid organic-inorganic chain: [(phen)Cu-μ-(κ2O:O'-VP2O10H3)2-Cu(phen)]n.

Authors :: Venegas-Yazigi D
Vega A
de la Barra KV
Saldias M
Le Fur E
Source :: Acta crystallographica. Section C, Crystal structure communications [Acta Crystallogr C] 2012 Jul; Vol. 68 (Pt 7), pp. m200-2. Date of Electronic Publication: 2012 Jun 26.
Publication Year :: 2012
Abstract: The structure of the title compound, poly[(dihydrogenphosphato-κO)(μ(3)-hydrogenphosphato)di-μ-oxido-(1,10-phenanthroline)copper(II)vanadium(V)], [CuV(HPO(4))(H(2)PO(4))O(2)(C(12)H(8)N(2))](n), is defined by [(phen)Cu-μ-(κ(2)O:O'-VP(2)O(10)H(3))(2)-Cu(phen)] units (phen is 1,10-phenanthroline), which are connected to neighbouring units through vanadyl bridges. Neighbouring chains have no covalent bonds between them, although they interdigitate through the phen groups via π-π interactions.

Language :: English
ISSN :: 1600-5759
Volume :: 68
Issue :: Pt 7
Database :: MEDLINE
Journal :: Acta crystallographica. Section C, Crystal structure communications
Publication Type :: Academic Journal
Accession number :: 22763689
Full Text :: https://doi.org/10.1107/S0108270112026005

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