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Desymmetrization of cyclohexadienones viad-camphor-derived triazolium salt catalyzed intramolecular Stetter reaction.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2012 May 23, pp. . Date of Electronic Publication: 2012 May 23. - Publication Year :
- 2012
- Publisher :
- Ahead of Print
-
Abstract
- Enantioselective desymmetrization of cyclohexadienones via a d-camphor-derived triazolium salt catalyzed intramolecular Stetter reaction was realized. With 10 mol% of camphor-derived triazolium salt E and 10 mol% of DIEA, various substituted cyclohexadienones proceeded through an intramolecular Stetter reaction, affording tricyclic products in moderate to good yields and excellent ee.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 22618513
- Full Text :
- https://doi.org/10.1039/c2cc32783j