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Anti-Markovnikov additions to N-allylic derivatives involving ammonium-carbenium superelectrophiles.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2012 Jun 14; Vol. 48 (47), pp. 5877-9. Date of Electronic Publication: 2012 May 08. - Publication Year :
- 2012
-
Abstract
- Anti-Markovnikov additions to non-conjugated unsaturated amines in superacid are reported. In situ NMR studies, DFT calculations and labelled substrates reactions support the involvement of new ammonium-carbenium superelectrophiles in this original process.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 48
- Issue :
- 47
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 22569949
- Full Text :
- https://doi.org/10.1039/c2cc32246c