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Photodissociation of N2O: excitation of 1A" states.
- Source :
-
The journal of physical chemistry. A [J Phys Chem A] 2012 Nov 26; Vol. 116 (46), pp. 11083-7. Date of Electronic Publication: 2012 May 14. - Publication Year :
- 2012
-
Abstract
- We investigate the contributions of the lowest two (1)A" states in the UV photodissociation of N(2)O employing three-dimensional potential energy surfaces and transition dipole moment functions. Because the transition dipole moments are much smaller than for the 2 (1)A' state, we conclude that excitation of the (1)A" states has a marginal effect. The dense vibrational spectrum of the quasi-bound 2(1)A" state possibly explains some of the tiny, noise-like structures of the measured absorption spectrum.
- Subjects :
- Photochemical Processes
Ultraviolet Rays
Nitrous Oxide chemistry
Quantum Theory
Subjects
Details
- Language :
- English
- ISSN :
- 1520-5215
- Volume :
- 116
- Issue :
- 46
- Database :
- MEDLINE
- Journal :
- The journal of physical chemistry. A
- Publication Type :
- Academic Journal
- Accession number :
- 22536943
- Full Text :
- https://doi.org/10.1021/jp302362m