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Targeted functionalisation of a hierarchically-structured porous coordination polymer crystal enhances its entire function.

Authors :
Hirai K
Furukawa S
Kondo M
Meilikhov M
Sakata Y
Sakata O
Kitagawa S
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2012 Jul 04; Vol. 48 (52), pp. 6472-4. Date of Electronic Publication: 2012 Apr 19.
Publication Year :
2012

Abstract

Spatiospecific functionalisation of a shell crystal was performed in a core-shell crystal of a porous coordination polymer (PCP) via post-synthetic modification (PSM). The shell crystal allowed the core crystal to selectively accumulate N,N-dimethylaniline (DMA) and afford the intense exciplex fluorescence.

Details

Language :
English
ISSN :
1364-548X
Volume :
48
Issue :
52
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
22516961
Full Text :
https://doi.org/10.1039/c2cc31421e