Back to Search
Start Over
A carbaboranylmercuric salt catalyzed reaction; highly regioselective cycloisomerization of 1,3-dienes.
- Source :
-
Organic letters [Org Lett] 2012 May 04; Vol. 14 (9), pp. 2266-9. Date of Electronic Publication: 2012 Apr 19. - Publication Year :
- 2012
-
Abstract
- The combination of carbaboranylmercuric chloride (new type of bulky Lewis acid) and silver triflate efficiently catalyzes cycloisomerization of 1,3-dienes at room temperature. The catalytic system gives allyl-substituted azacycles and cycloalkanes in excellent yields with high to complete regioselectivity.
Details
- Language :
- English
- ISSN :
- 1523-7052
- Volume :
- 14
- Issue :
- 9
- Database :
- MEDLINE
- Journal :
- Organic letters
- Publication Type :
- Academic Journal
- Accession number :
- 22515376
- Full Text :
- https://doi.org/10.1021/ol300678r