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Coordination-network-based ionic plastic crystal for anhydrous proton conductivity.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2012 May 09; Vol. 134 (18), pp. 7612-5. Date of Electronic Publication: 2012 Apr 30. - Publication Year :
- 2012
-
Abstract
- An ionic coordination network consisting of protonated imidazole and anionic one-dimensional chains of Zn(2+) phosphate was synthesized. The compound possesses highly mobile ions in the crystal lattice and behaves as an ionic plastic crystal. The dynamic behavior provides a proton conductivity of 2.6 × 10(-4) S cm(-1) at 130 °C without humidity.
Details
- Language :
- English
- ISSN :
- 1520-5126
- Volume :
- 134
- Issue :
- 18
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 22512400
- Full Text :
- https://doi.org/10.1021/ja301875x