Back to Search
Start Over
High-performance sodium-ion pseudocapacitors based on hierarchically porous nanowire composites.
- Source :
-
ACS nano [ACS Nano] 2012 May 22; Vol. 6 (5), pp. 4319-27. Date of Electronic Publication: 2012 Apr 19. - Publication Year :
- 2012
-
Abstract
- Electrical energy storage plays an increasingly important role in modern society. Current energy storage methods are highly dependent on lithium-ion energy storage devices, and the expanded use of these technologies is likely to affect existing lithium reserves. The abundance of sodium makes Na-ion-based devices very attractive as an alternative, sustainable energy storage system. However, electrodes based on transition-metal oxides often show slow kinetics and poor cycling stability, limiting their use as Na-ion-based energy storage devices. The present paper details a new direction for electrode architectures for Na-ion storage. Using a simple hydrothermal process, we synthesized interpenetrating porous networks consisting of layer-structured V(2)O(5) nanowires and carbon nanotubes (CNTs). This type of architecture provides facile sodium insertion/extraction and fast electron transfer, enabling the fabrication of high-performance Na-ion pseudocapacitors with an organic electrolyte. Hybrid asymmetric capacitors incorporating the V(2)O(5)/CNT nanowire composites as the anode operated at a maximum voltage of 2.8 V and delivered a maximum energy of ∼40 Wh kg(-1), which is comparable to Li-ion-based asymmetric capacitors. The availability of capacitive storage based on Na-ion systems is an attractive, cost-effective alternative to Li-ion systems.
- Subjects :
- Electrodes
Microscopy, Electron, Scanning
Nanowires
Sodium chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 1936-086X
- Volume :
- 6
- Issue :
- 5
- Database :
- MEDLINE
- Journal :
- ACS nano
- Publication Type :
- Academic Journal
- Accession number :
- 22471878
- Full Text :
- https://doi.org/10.1021/nn300920e