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Facile synthesis of 2-alkyl/aryloxy-2H-azirines and their application in the synthesis of pyrroles.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2012 Apr 25; Vol. 48 (33), pp. 3996-8. Date of Electronic Publication: 2012 Mar 15. - Publication Year :
- 2012
-
Abstract
- Free carbenes generated from α-diazo oxime ethers by photolysis undergo facile N-O insertion to afford 2-alkyl/aryloxy-2H-azirines in good to excellent yields. This method allowed for the development of a tandem reaction for pyrrole synthesis via 1,3-dipolar cycloaddition.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 48
- Issue :
- 33
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 22421951
- Full Text :
- https://doi.org/10.1039/c2cc30490b