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Dichloridobis(4-pyridylmethyl 1H-pyrrole-2-carboxyl-ate-κN)zinc.
- Source :
-
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2012 Mar 01; Vol. 68 (Pt 3), pp. m323. Date of Electronic Publication: 2012 Feb 24. - Publication Year :
- 2012
-
Abstract
- In the title mol-ecule, [ZnCl(2)(C(11)H(10)N(2)O(2))(2)], the Zn(II) ion, situated on a twofold axis, is in a distorted tetra-hedral coordination environment formed by two chloride anions and two pyridine N atoms of the two organic ligands. In the pyrrole-2-carboxyl-ate unit, the pyrrole N-H group and the carbonyl group point approximately in the same direction. The dihedral angle between the two pyridine rings is 54.8 (3)°. The complex mol-ecules are connected into chains extending along [101] by N-H⋯Cl hydrogen bonds. The chains are further assembled into (-101) layers by C-H⋯O and C-H⋯Cl inter-actions.
Details
- Language :
- English
- ISSN :
- 1600-5368
- Volume :
- 68
- Issue :
- Pt 3
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section E, Structure reports online
- Publication Type :
- Academic Journal
- Accession number :
- 22412460
- Full Text :
- https://doi.org/10.1107/S1600536812001353