Back to Search Start Over

Dichloridobis(4-pyridylmethyl 1H-pyrrole-2-carboxyl-ate-κN)zinc.

Authors :
Li C
Zhang G
Yin Z
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2012 Mar 01; Vol. 68 (Pt 3), pp. m323. Date of Electronic Publication: 2012 Feb 24.
Publication Year :
2012

Abstract

In the title mol-ecule, [ZnCl(2)(C(11)H(10)N(2)O(2))(2)], the Zn(II) ion, situated on a twofold axis, is in a distorted tetra-hedral coordination environment formed by two chloride anions and two pyridine N atoms of the two organic ligands. In the pyrrole-2-carboxyl-ate unit, the pyrrole N-H group and the carbonyl group point approximately in the same direction. The dihedral angle between the two pyridine rings is 54.8 (3)°. The complex mol-ecules are connected into chains extending along [101] by N-H⋯Cl hydrogen bonds. The chains are further assembled into (-101) layers by C-H⋯O and C-H⋯Cl inter-actions.

Details

Language :
English
ISSN :
1600-5368
Volume :
68
Issue :
Pt 3
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
22412460
Full Text :
https://doi.org/10.1107/S1600536812001353