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Improved hydrogen release from ammonia-borane with ZIF-8.

Authors :
Zhong RQ
Zou RQ
Nakagawa T
Janicke M
Semelsberger TA
Burrell AK
Del Sesto RE
Source :
Inorganic chemistry [Inorg Chem] 2012 Mar 05; Vol. 51 (5), pp. 2728-30. Date of Electronic Publication: 2012 Feb 17.
Publication Year :
2012

Abstract

The promotion for hydrogen release from ammonia-borane (AB) was observed in the presence of ZIF-8. Even at concentrations of ZIF-8 as low as 0.25 mol %, a reduction of the onset temperature for dehydrogenation accompanies an increase in both the rate and amount of hydrogen released from AB.

Details

Language :
English
ISSN :
1520-510X
Volume :
51
Issue :
5
Database :
MEDLINE
Journal :
Inorganic chemistry
Publication Type :
Academic Journal
Accession number :
22339585
Full Text :
https://doi.org/10.1021/ic202562b