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Ag(nic)2 (nic = nicotinate): a spin-canted quasi-2D antiferromagnet composed of square-planar S = 1/2 Ag(II) ions.

Authors :
Manson JL
Woods TJ
Lapidus SH
Stephens PW
Southerland HI
Zapf VS
Singleton J
Goddard PA
Lancaster T
Steele AJ
Blundell SJ
Source :
Inorganic chemistry [Inorg Chem] 2012 Feb 20; Vol. 51 (4), pp. 1989-91. Date of Electronic Publication: 2012 Jan 27.
Publication Year :
2012

Abstract

Square-planar S = 1/2 Ag(II) ions in polymeric Ag(nic)(2) are linked by bridging nic monoanions to yield 2D corrugated sheets. Long-range magnetic order occurs below T(N) = 11.8(2) K due to interlayer couplings that are estimated to be about 30 times weaker than the intralayer exchange interaction.

Details

Language :
English
ISSN :
1520-510X
Volume :
51
Issue :
4
Database :
MEDLINE
Journal :
Inorganic chemistry
Publication Type :
Academic Journal
Accession number :
22283606
Full Text :
https://doi.org/10.1021/ic202600n