Mimicking zeolite to its core: porous sodalite cages as hangers for pendant trimeric M3(OH) clusters (M = Mg, Mn, Co, Ni, Cd).

Authors :: Zheng ST
Wu T
Zuo F
Chou C
Feng P
Bu X
Source :: Journal of the American Chemical Society [J Am Chem Soc] 2012 Feb 01; Vol. 134 (4), pp. 1934-7. Date of Electronic Publication: 2012 Jan 19.
Publication Year :: 2012
Abstract: A new class of zeolite-type porous materials in which 3D frameworks are covalently functionalized with crystallographically ordered pendant metal clusters have been synthesized. This work demonstrates a new paradigm for and the feasibility of functionalizing zeolite-type frameworks through the conversion of extraframework sites in mineral zeolites into part of the framework for occupation by dangling metal clusters in metal-organic frameworks.<br /> (© 2012 American Chemical Society)

Subjects :: Models, Molecular
Porosity
Surface Properties
Hydroxides chemistry
Magnesium chemistry
Metals, Heavy chemistry
Zeolites chemistry

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