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Chiral Brønsted acid catalyzed enantioselective propargylation of aldehydes with allenylboronate.
- Source :
-
Organic letters [Org Lett] 2012 Feb 17; Vol. 14 (4), pp. 1142-5. Date of Electronic Publication: 2012 Jan 24. - Publication Year :
- 2012
-
Abstract
- A highly enantioselective chiral Brønsted acid catalyzed propargylation of aldehydes with allenylboronate is described. The reaction is shown to be practical and quite general with a broad substrate scope covering aryl, polyaryl, heteroaryl, α,β-unsaturated, and aliphatic aldehydes.
Details
- Language :
- English
- ISSN :
- 1523-7052
- Volume :
- 14
- Issue :
- 4
- Database :
- MEDLINE
- Journal :
- Organic letters
- Publication Type :
- Academic Journal
- Accession number :
- 22273041
- Full Text :
- https://doi.org/10.1021/ol300075n