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Preparation and relaxation of very stable glassy states of a simulated liquid.

Authors :
Jack RL
Hedges LO
Garrahan JP
Chandler D
Source :
Physical review letters [Phys Rev Lett] 2011 Dec 30; Vol. 107 (27), pp. 275702. Date of Electronic Publication: 2011 Dec 27.
Publication Year :
2011

Abstract

We prepare metastable glassy states in a model glass former made of Lennard-Jones particles by sampling biased ensembles of trajectories with low dynamical activity. These trajectories form an inactive dynamical phase whose "fast" vibrational degrees of freedom are maintained at thermal equilibrium by contact with a heat bath, while the "slow" structural degrees of freedom are located in deep valleys of the energy landscape. We examine the relaxation to equilibrium and the vibrational properties of these metastable states. The glassy states we prepare by our trajectory sampling method are very stable to thermal fluctuations and also more mechanically rigid than low-temperature equilibrated configurations.

Details

Language :
English
ISSN :
1079-7114
Volume :
107
Issue :
27
Database :
MEDLINE
Journal :
Physical review letters
Publication Type :
Academic Journal
Accession number :
22243318
Full Text :
https://doi.org/10.1103/PhysRevLett.107.275702