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(μ-Piperazine-1,4-dicarbodithio-ato-κS,S:S,S)bis-[bis-(triphenyl-phos-phane-κP)gold(I)] chloro-form disolvate.
- Source :
-
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2011 Nov; Vol. 67 (Pt 11), pp. m1629-30. Date of Electronic Publication: 2011 Oct 29. - Publication Year :
- 2011
-
Abstract
- In the title compound, [Au(2)(C(6)H(8)N(2)S(4))(C(18)H(15)P)(4)]·2CHCl(3), the digold complex resides on a crystallographic inversion center and co-crystallizes with two mol-ecules of chloro-form solvent. The piperazine-1,4-dicarbodithio-ate linker has an almost ideal chair conformation. The geometry about the gold atoms is severely distorted tetra-hedral punctuated by a very acute S-Au-S bite angle.
Details
- Language :
- English
- ISSN :
- 1600-5368
- Volume :
- 67
- Issue :
- Pt 11
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section E, Structure reports online
- Publication Type :
- Academic Journal
- Accession number :
- 22219852
- Full Text :
- https://doi.org/10.1107/S1600536811044229