Back to Search Start Over

Tetra-aqua-bis-[N,N'-bis-(pyridin-3-yl-methyl-idene)benzene-1,4-diamine]-zinc dinitrate 1.49-hydrate.

Authors :
Kong L
Yu H
Zhang J
Cui W
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2011 Dec 01; Vol. 67 (Pt 12), pp. m1752. Date of Electronic Publication: 2011 Nov 12.
Publication Year :
2011

Abstract

In the title compound, [Zn(C(18)H(14)N(4))(2)(H(2)O)(4)](NO(3))(2)·1.49H(2)O, the Zn(II) atom, lying on an inversion center, is coordinated by two N atoms from two N,N'-bis-(pyridin-3-yl-methyl-idene)benzene-1,4-diamine ligands and four water mol-ecules in a distorted octa-hedral geometry. The nitrate anion is disordered over two sets of sites, with an occupancy ratio of 0.744 (4):0.256 (4). The uncoordinated water mol-ecule is also disordered with an occupancy factor of 0.744 (4). O-H⋯O and O-H⋯N hydrogen bonds link the complex cations, nitrate anions and uncoordinated water mol-ecules into a supra-molecular layer parallel to (102).

Details

Language :
English
ISSN :
1600-5368
Volume :
67
Issue :
Pt 12
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
22199550
Full Text :
https://doi.org/10.1107/S1600536811046915