Increased catalytic activity of surface-immobilized palladium complexes in the fluorogenic deprotection of an alloc-derivatized coumarin.

Authors :: Fernandes A
Hensenne P
Mathy B
Guo W
Nysten B
Jonas AM
Riant O
Source :: Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2012 Jan 16; Vol. 18 (3), pp. 788-92. Date of Electronic Publication: 2011 Dec 14.
Publication Year :: 2012
Abstract: Catalytic surfaces have been prepared by complexation of palladium on self-assembled terpyridine monolayers on silicon. A reaction-based fluorogenic probe was developed to allow facile visualization of the catalytic potential of the surface. Superior activity of the immobilized catalyst compared with the homogeneous control reactions is demonstrated.<br /> (Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Subjects :: Catalysis
Coordination Complexes chemistry
Coumarins chemistry
Molecular Structure
Coordination Complexes chemical synthesis
Coumarins chemical synthesis
Palladium chemistry
Silicon chemistry

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