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A four coordinate parent imide via a titanium nitridyl.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2012 Feb 01; Vol. 48 (10), pp. 1529-31. Date of Electronic Publication: 2011 Oct 05. - Publication Year :
- 2012
-
Abstract
- Treatment of d(1) [(nacnac)TiCl(Ntol(2))] with NaN(3) results in NaCl formation and N(2) ejection to yield the first four coordinate, parent imide [(nacnac)Ti=NH(Ntol(2))] (nacnac(-)=[ArNC(CH(3))](2)CH, Ar = 2,6-iPr(2)C(6)H(3), tol = 4-CH(3)C(6)H(4)).<br /> (This journal is © The Royal Society of Chemistry 2012)
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 48
- Issue :
- 10
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 21971561
- Full Text :
- https://doi.org/10.1039/c1cc14574f