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Assessment of the electronic properties of P ligands stemming from secondary phosphine oxides.
- Source :
-
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2011 Nov 04; Vol. 17 (45), pp. 12729-40. Date of Electronic Publication: 2011 Sep 29. - Publication Year :
- 2011
-
Abstract
- We report the study of the net donating ability of monodentate and bidentate P ligands stemming from secondary phosphine oxides (SPOs). We experimentally measured and/or calculated the frequencies of CO stretching modes of various metal carbonyl complexes. The inferred electronic properties of the ligands span an unprecedented range, going from π-accepting phosphite-like compounds, to extremely electron-donating ligands outclassing N-heterocyclic carbenes.<br /> (Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1521-3765
- Volume :
- 17
- Issue :
- 45
- Database :
- MEDLINE
- Journal :
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Publication Type :
- Academic Journal
- Accession number :
- 21956620
- Full Text :
- https://doi.org/10.1002/chem.201101663