The photoionisation of propargylene and diazopropyne.

Authors :: Steinbauer M
Lang M
Fischer I
de Miranda BK
Romanzin C
Alcaraz C
Source :: Physical chemistry chemical physics : PCCP [Phys Chem Chem Phys] 2011 Oct 28; Vol. 13 (40), pp. 17956-9. Date of Electronic Publication: 2011 Sep 20.
Publication Year :: 2011
Abstract: The photoionisation of the C(3)H(2) isomer propargylene was studied using synchrotron radiation and coincidence techniques. An adiabatic ionisation energy (IE(ad)) of 8.99 ± 0.02 eV was determined. The precursor diazopropyne was investigated as well. Ionisation and appearance energies were measured.<br /> (This journal is © the Owner Societies 2011)