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Methods for the preparation of allenes employing indium- and zinc-mediated dehalogenation reactions in aqueous solutions.
- Source :
-
The Journal of organic chemistry [J Org Chem] 2011 Oct 21; Vol. 76 (20), pp. 8518-23. Date of Electronic Publication: 2011 Sep 21. - Publication Year :
- 2011
-
Abstract
- Simple and mild methods for the synthesis of allenes, employing indium- and zinc-mediated dehalogenation reactions of vicinal dihalides in an aqueous solvent, are described. By using these procedures, various allenylmethyl aryl ethers and monosubstituted allenes have been prepared in good to excellent yields.
- Subjects :
- Alkadienes pharmacology
Antineoplastic Agents pharmacology
Catalysis
Ethers pharmacology
Humans
Indium chemistry
Molecular Structure
Neoplasms drug therapy
Solutions
Stereoisomerism
Water
Zinc chemistry
Alkadienes chemical synthesis
Antineoplastic Agents chemical synthesis
Chemistry, Pharmaceutical methods
Ethers chemical synthesis
Green Chemistry Technology
Halogens chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 1520-6904
- Volume :
- 76
- Issue :
- 20
- Database :
- MEDLINE
- Journal :
- The Journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 21895004
- Full Text :
- https://doi.org/10.1021/jo2015104