Synthesis and vibrational spectroscopic analysis of some Hofmann type clathrates.

Authors :: Parlak C
Şenyel M
Source :: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy [Spectrochim Acta A Mol Biomol Spectrosc] 2011 Nov; Vol. 82 (1), pp. 383-8. Date of Electronic Publication: 2011 Jul 26.
Publication Year :: 2011
Abstract: New Hofmann type clathrates in the form of M(pp)(2)Ni(CN)(4)·2G (where pp = 1-phenylpiperazine, G = 1,4-dioxane and M = Ni, Co or Cd) have been prepared in powder form and their FT-IR and FT-Raman spectra are reported. The results suggest that the present compounds are similar in structure to the Hofmann type clathrates and their structures consist of conjugated polymeric layers of |M-Ni(CN)(4)|(∞) with the pp bound to the metal (M) atom.<br /> (Copyright © 2011 Elsevier B.V. All rights reserved.)

Subjects :: Cyanides chemistry
Dioxanes chemistry
Ions
Ligands
Metals chemistry
Molecular Conformation
Nickel chemistry
Piperazines chemistry
Polymers chemistry
Spectroscopy, Fourier Transform Infrared methods
Spectrum Analysis, Raman methods
Vibration
Spectrophotometry methods

Language :: English
ISSN :: 1873-3557
Volume :: 82
Issue :: 1
Database :: MEDLINE
Journal :: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
Publication Type :: Academic Journal
Accession number :: 21820947
Full Text :: https://doi.org/10.1016/j.saa.2011.07.067

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