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Bis(2-amino-1,3-benzothia-zol-3-ium) tetra-chloridozincate(II).

Authors :
Kefi R
Jeanneau E
Lefebvre F
Ben Nasr C
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2011 Jun 01; Vol. 67 (Pt 6), pp. m654-5. Date of Electronic Publication: 2011 May 07.
Publication Year :
2011

Abstract

The asymmetric unit of the title compound, (C(7)H(7)N(2)S)(2)[ZnCl(4)], contains a network of 2-amino-benzothia-zolium cations and tetra-hedral [ZnCl(4)](2-) anions. The crystal packing is influenced by cation-to-anion N-H⋯Cl and C-H⋯Cl hydrogen bonds. The [ZnCl(4)](2-) anions have a distorded tetra-hedral geometry. Inter-molecular π-π stacking inter-actions are present between neighboring benzene rings, thia-zole and benzene rings and neighboring thia-zole rings [centroid-centroid distances = 3.711 (2), 3.554 (1), 3.536 (2) and 3.572 (1) Å].

Details

Language :
English
ISSN :
1600-5368
Volume :
67
Issue :
Pt 6
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
21754568
Full Text :
https://doi.org/10.1107/S1600536811015753