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Glycoside bond formation via acid-base catalysis.

Authors :
Kumar A
Kumar V
Dere RT
Schmidt RR
Source :
Organic letters [Org Lett] 2011 Jul 15; Vol. 13 (14), pp. 3612-5. Date of Electronic Publication: 2011 Jun 15.
Publication Year :
2011

Abstract

Acid-base catalyzed glycosyl donor and then glycosyl acceptor activation with phenylboron difluoride or diphenylboron fluoride permits hydrogen bond mediated intramolecular S(N)2-type glycosidation in generally high anomeric selectivity.<br /> (© 2011 American Chemical Society)

Details

Language :
English
ISSN :
1523-7052
Volume :
13
Issue :
14
Database :
MEDLINE
Journal :
Organic letters
Publication Type :
Academic Journal
Accession number :
21675711
Full Text :
https://doi.org/10.1021/ol201231v