Remarkable metal-complexed phosphorus analogues of the cyclopropenylcarbene-cyclobutadiene rearrangement.

Authors :: Lyaskovskyy V
Elders N
Ehlers AW
Lutz M
Slootweg JC
Lammertsma K
Source :: Journal of the American Chemical Society [J Am Chem Soc] 2011 Jun 29; Vol. 133 (25), pp. 9704-7. Date of Electronic Publication: 2011 Jun 07.
Publication Year :: 2011
Abstract: In situ-generated metal carbonyl-complexed cyclopropenylphosphinidenes undergo a sequence of structural changes leading to phosphorus analogues of Pettit's seminal (η(4)-cyclobutadiene)iron tricarbonyl complex via multiple valence isomers along the reaction pathway and the elimination of one molecule of carbon monoxide.

Subjects :: Butadienes
Cyclobutanes
Cyclopropanes
Methane analogs & derivatives
Organic Chemistry Phenomena
Coordination Complexes chemistry
Phosphines chemistry
Phosphorus chemistry

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