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4-{[2-(2,4-Dinitro-phen-yl)hydrazinyl-idene]meth-yl}phenol ethanol hemisolvate.

Authors :
Zhai XR
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2010 Nov 13; Vol. 66 (Pt 12), pp. o3142. Date of Electronic Publication: 2010 Nov 13.
Publication Year :
2010

Abstract

In the title compound, C(13)H(10)N(4)O(5)·0.5C(2)H(5)OH, the two benzene rings form a dihedral angle of 4.29 (9)°. The ethanol solvent mol-ecule was treated as disordered between two orientations related by symmetry (center of inversion), with occupancies fixed at 0.5. The crystal packing, stabilized by inter-molecular O-H⋯O and N-H⋯O hydrogen bonds and π-π inter-actions [indicated by the short distance of 3.7299 (7) Å between the centroids of benzene rings from neighbouring mol-ecules], exhibits short inter-molecular O⋯O contacts of 2.8226 (3) Å.

Details

Language :
English
ISSN :
1600-5368
Volume :
66
Issue :
Pt 12
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
21589441
Full Text :
https://doi.org/10.1107/S1600536810045782