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Azido-{2-[bis-(2-hy-droxy-eth-yl)amino]-ethano-lato-κN,O,O',O''}cobalt(II).

Authors :
Liu YJ
Yang HX
Yuan J
Wang X
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2010 Nov 20; Vol. 66 (Pt 12), pp. m1617. Date of Electronic Publication: 2010 Nov 20.
Publication Year :
2010

Abstract

In the title complex, [Co(C(6)H(14)NO(3))(N(3))] or [Co(teaH(2))N(3)], the Co(II) atom resides in a trigonal-bipymidal O(3)N(2) environment formed by three O atoms and one N atom from a simply deprotonated tetra-dentate triethano-lamine ligand, and one N atom from an azide ligand. The O atoms define the equatorial plane whereas both N atoms are in axial positions. The mononuclear units are linked through O-H⋯O hydrogen-bonding inter-actions between the ethanol OH groups and the ethano-late O atom of a neighbouring complex into chains running parallel to [010].

Details

Language :
English
ISSN :
1600-5368
Volume :
66
Issue :
Pt 12
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
21589293
Full Text :
https://doi.org/10.1107/S1600536810047100