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Tetra-aqua(2,2'-bipyridine-κN,N')magnesium(II) bis-(4-bromo-benzoate).
- Source :
-
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2010 Oct 23; Vol. 66 (Pt 11), pp. m1426. Date of Electronic Publication: 2010 Oct 23. - Publication Year :
- 2010
-
Abstract
- In the complex cation of the title compound, [Mg(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(4)BrO(2))(2), the Mg(II) atom is coordinated by two N atoms from a 2,2'-bipyridine ligand and four water O atoms in a distorted MgN(2)O(4) octa-hedral geometry. The cation is located on a special position on a twofold rotation axis which passes through the Mg(II) atom and the centroid of the 2,2'-bipyridine ligand. The 2,2'-bipyridine ligands exhibit nearly perfect coplanarity (r.m.s. deviation = 0.0035 Å) . In the crystal, O-H⋯O and C-H⋯O, C-H⋯Br hydrogen bonds and π-π stacking inter-actions [mean inter-planar distance of 3.475 (6) Å between adjacent 2,2'-bipyridine ligands] link the cations and anions into a three-dimensional supra-molecular network. One Br atom is disordered over two sites with occupancy factors of 0.55 and 0.45.
Details
- Language :
- English
- ISSN :
- 1600-5368
- Volume :
- 66
- Issue :
- Pt 11
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section E, Structure reports online
- Publication Type :
- Academic Journal
- Accession number :
- 21588852
- Full Text :
- https://doi.org/10.1107/S1600536810041474