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[2,6-Bis(6-methyl-quinolin-2-yl)pyridine-κN,N',N'']dichloridomanganese(II).
- Source :
-
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2010 Sep 25; Vol. 66 (Pt 10), pp. m1298. Date of Electronic Publication: 2010 Sep 25. - Publication Year :
- 2010
-
Abstract
- In the mol-ecule of the title compound, [MnCl(2)(C(25)H(19)N(3))], the three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Mn(II) atom is 34% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). One of the Cl atoms is disordered over two positions in a 0.82 (3):0.18 (3) ratio. Weak inter-molecular C-H⋯Cl hydrogen bonding occurs in the crystal structure.
Details
- Language :
- English
- ISSN :
- 1600-5368
- Volume :
- 66
- Issue :
- Pt 10
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section E, Structure reports online
- Publication Type :
- Academic Journal
- Accession number :
- 21587437
- Full Text :
- https://doi.org/10.1107/S1600536810037037