Back to Search
Start Over
Poly[(μ(2)-azido-κN:N)[μ(2)-5-(8-quinolyl-oxy-methyl)tetra-zolato-κN,O,N:N]zinc(II)].
- Source :
-
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2009 May 14; Vol. 65 (Pt 6), pp. m632. Date of Electronic Publication: 2009 May 14. - Publication Year :
- 2009
-
Abstract
- In the title compound, [Zn(C(11)H(8)N(5)O)(N(3))](n), the Zn atom is hexa-coordinated by five N atoms and one O atom in a distorted octa-hedral geometry. The chelating 5-(8-quinolyloxymeth-yl)tetra-zolate ligands are approximately planar, with a dihedral angle of 3.6 (2)° between the quinoline and tetra-zole planes. Adjacent Zn atoms are linked by two bridging azide ligands across a centre of inversion, and further coordination by one N atom of an adjacent tetra-zole unit forms two-dimensional frameworks in (100). C-H⋯N inter-actions exist between ligands in neighbouring layers.
Details
- Language :
- English
- ISSN :
- 1600-5368
- Volume :
- 65
- Issue :
- Pt 6
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section E, Structure reports online
- Publication Type :
- Academic Journal
- Accession number :
- 21583000
- Full Text :
- https://doi.org/10.1107/S1600536809016924