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Octa-aqua-bis(μ(2)-1H-pyrazole-3,5-di-carboxyl-ato)tricopper(II) tetra-hydrate.

Authors :
Li ZG
Li SA
Liu DQ
Huang YH
Xu JW
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2010 Jan 30; Vol. 66 (Pt 2), pp. m216. Date of Electronic Publication: 2010 Jan 30.
Publication Year :
2010

Abstract

In the trinucler Cu(II) complex mol-ecule of the title compound, [Cu(3)(C(5)HN(2)O(4))(2)(H(2)O)(8)]·4H(2)O, the central Cu(II) atom is located on an inversion centre and is coordinated in a distorted octa-hedral geometry. The equatorial sites are occupied by two N and two O atoms from two pyrazole-3,5-dicarboxyl-ate ligands and the axial positions are occupied by two water mol-ecules. The two other symmetry-related Cu(II) atoms are penta-coordinated and assume a square-pyramidal geometry. In the crystal structure, coordinated and uncoordinated water mol-ecules and carboxyl-ate O atoms are linked by O-H⋯O hydrogen bonds.

Details

Language :
English
ISSN :
1600-5368
Volume :
66
Issue :
Pt 2
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
21579677
Full Text :
https://doi.org/10.1107/S1600536810001595