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Octa-aqua-bis(μ(2)-1H-pyrazole-3,5-di-carboxyl-ato)tricopper(II) tetra-hydrate.
- Source :
-
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2010 Jan 30; Vol. 66 (Pt 2), pp. m216. Date of Electronic Publication: 2010 Jan 30. - Publication Year :
- 2010
-
Abstract
- In the trinucler Cu(II) complex mol-ecule of the title compound, [Cu(3)(C(5)HN(2)O(4))(2)(H(2)O)(8)]·4H(2)O, the central Cu(II) atom is located on an inversion centre and is coordinated in a distorted octa-hedral geometry. The equatorial sites are occupied by two N and two O atoms from two pyrazole-3,5-dicarboxyl-ate ligands and the axial positions are occupied by two water mol-ecules. The two other symmetry-related Cu(II) atoms are penta-coordinated and assume a square-pyramidal geometry. In the crystal structure, coordinated and uncoordinated water mol-ecules and carboxyl-ate O atoms are linked by O-H⋯O hydrogen bonds.
Details
- Language :
- English
- ISSN :
- 1600-5368
- Volume :
- 66
- Issue :
- Pt 2
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section E, Structure reports online
- Publication Type :
- Academic Journal
- Accession number :
- 21579677
- Full Text :
- https://doi.org/10.1107/S1600536810001595