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Tetra-imidazole-bis(trichloro-acetato)copper(II).

Authors :
Li LM
Guo HM
Jian FF
Zhang ZH
Zhang N
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2010 May 22; Vol. 66 (Pt 6), pp. m682. Date of Electronic Publication: 2010 May 22.
Publication Year :
2010

Abstract

The title compound, [Cu(C(2)Cl(3)O(2))(2)(C(3)H(4)N(2))(4)], was prepared by the reaction of imidazole and trichloro-acetatocopper(II). The Cu(II) atom adopts a distorted octa-hedral coordination geometry, binding the N atoms of four imidazole ligands and the carboxyl-ate O atoms of two trichloro-acetate anions. The mol-ecular structure and packing are stabilized by N-H⋯O hydrogen-bonding inter-actions. Close inter-molecular Cl⋯Cl contacts [3.498 (3) Å] are also found in the structure.

Details

Language :
English
ISSN :
1600-5368
Volume :
66
Issue :
Pt 6
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
21579322
Full Text :
https://doi.org/10.1107/S1600536810017459