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catena-Poly[[diaqua-strontium]-bis-(μ-2-bromo-benzoato)-κO,O':O';κO:O,O'].
- Source :
-
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2009 Nov 04; Vol. 65 (Pt 12), pp. m1500. Date of Electronic Publication: 2009 Nov 04. - Publication Year :
- 2009
-
Abstract
- The hydro-thermal reaction of SrCO(3) and 2-bromo-benzoic acid in CH(3)OH-H(2)O afforded the Sr(II) title polymeric complex, [Sr(C(7)H(4)BrO(2))(2)(H(2)O)(2)](n). Within the coordination sphere, the Sr(II) ion is located on a crystallographic twofold axis, and is coordinated by eight O atoms from two water mol-ecules and four carboxyl-ate groups of 2-bromo-benzoate ligands in an irregular coordination geometry. Two μ(3)-carboxyl-ate groups of the 2-bromo-benzoate anions bridge two symmetry-related Sr(II) atoms, giving rise to a chain structure extending along [001]. The polymeric chains are connected via O-H⋯O and O-H⋯Br hydrogen bonds inter-actions into a three-dimensional supra-molecular network.
Details
- Language :
- English
- ISSN :
- 1600-5368
- Volume :
- 65
- Issue :
- Pt 12
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section E, Structure reports online
- Publication Type :
- Academic Journal
- Accession number :
- 21578551
- Full Text :
- https://doi.org/10.1107/S1600536809045395