Back to Search
Start Over
Photoswitchable intramolecular through-space magnetic interaction.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2011 Jun 01; Vol. 133 (21), pp. 8162-4. Date of Electronic Publication: 2011 May 11. - Publication Year :
- 2011
-
Abstract
- The interaction between two TEMPO spin centers connected to a photoswitchable overcrowded alkene changes from noncoupled (three-line EPR spectrum) in the trans state, where the two spin centers are separated by ∼22 Å, to strongly coupled (five-line EPR spectrum) in the cis state, where the separation is ∼7 Å, upon photoswitching. Importantly, the performance of the alkene switching unit is essentially unaffected by the spin centers.<br /> (© 2011 American Chemical Society)
Details
- Language :
- English
- ISSN :
- 1520-5126
- Volume :
- 133
- Issue :
- 21
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 21542643
- Full Text :
- https://doi.org/10.1021/ja202882q