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Aqua-[bis-(2-ethyl-5-methyl-1H-imidazol-4-yl-κN)methane]-oxalatocopper(II) dihydrate.
- Source :
-
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2011 Jan 15; Vol. 67 (Pt 2), pp. m172. Date of Electronic Publication: 2011 Jan 15. - Publication Year :
- 2011
-
Abstract
- In the title compound, [Cu(C(2)O(4))(C(13)H(20)N(4))(H(2)O)]·2H(2)O, the Cu(II) atom exhibits a distorted square-pyramidal geometry with the two N atoms of the imidazole ligand and the two O atoms of the oxalate ligand forming the basal plane, while the O atom of the coordinated water mol-ecule is in an apical position. The Cu(II) atom is shifted 0.232 (2) Å out of the basal plane toward the water mol-ecule. The asymmetric unit is completed by two solvent water mol-ecules. These water mol-ecules participate in the formation of an intricate three-dimensionnal network of hydrogen bonds involving the coordinated water mol-ecule and the NH groups.
Details
- Language :
- English
- ISSN :
- 1600-5368
- Volume :
- 67
- Issue :
- Pt 2
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section E, Structure reports online
- Publication Type :
- Academic Journal
- Accession number :
- 21522849
- Full Text :
- https://doi.org/10.1107/S1600536811001012