Back to Search Start Over

Diaqua-bis-(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-κN,O)cobalt(II) 3.5-hydrate.

Authors :
Li SJ
Miao DL
Song WD
Tong SW
An JB
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2010 Dec 24; Vol. 67 (Pt 1), pp. m106-7. Date of Electronic Publication: 2010 Dec 24.
Publication Year :
2010

Abstract

In the title complex, [Co(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Co(II) cation is six-coordinated by two H(2)pimda(-) ligands (H(3)pimda is 2-propyl-1H-imidazole-4,5-carboxylic acid) and two water mol-ecules in a distorted octa-hedral environment. The crystal structures features a three-dimensional network stabilized by extensive O-H⋯O and N-H⋯O hydrogen bonds. The propyl groups of the ligands are disordered over two sets of sites with refined occupancies of 0.673 (8):0.327 (8) and 0.621 (17):0.379 (17). One of the water mol-ecules is located on a site with half-occupancy.

Details

Language :
English
ISSN :
1600-5368
Volume :
67
Issue :
Pt 1
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
21522520
Full Text :
https://doi.org/10.1107/S1600536810052785