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Bis(2-amino-5-chloro-pyridinium) tetra-chloridozincate.

Authors :
Kefi R
Jeanneau E
Lefebvre F
Ben Nasr C
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2011 Feb 23; Vol. 67 (Pt 3), pp. m355-6. Date of Electronic Publication: 2011 Feb 23.
Publication Year :
2011

Abstract

The asymmetric unit of the title compound, (C(5)H(6)ClN(2))(2)[ZnCl(4)], contains two 2-amino-5-chloro-pyridinium cations and one [ZnCl(4)](2-) dianion which are held together by N-H⋯Cl and C-H⋯Cl hydrogen bonds. The [ZnCl(4)](2-) anions have a distorted tetra-hedral geometry. Weak inter-molecular π-π stacking inter-actions exist between neighbouring aromatic rings of the cations with a centroid-centroid distance of 3.712 (7) Å.

Details

Language :
English
ISSN :
1600-5368
Volume :
67
Issue :
Pt 3
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
21522283
Full Text :
https://doi.org/10.1107/S1600536811005691